Math 2.0

Integral equations Integro-differential equations Example

Smoluchowski coagulation equation

Example

Let n(x,t)≥0n(x, t) \ge 0 be the number density of clusters of mass x>0x > 0 at time t≥0t \ge 0. Let the coagulation kernel K(x,y)=K(y,x)≥0K(x, y) = K(y, x) \ge 0 be the rate at which clusters of masses xx and yy merge. The continuous Smoluchowski coagulation equation is ∂n(x,t)∂t=12∫0xK(x−y,y) n(x−y,t) n(y,t) dy−n(x,t)∫0∞K(x,y) n(y,t) dy.\frac{\partial n(x, t)}{\partial t} = \frac12 \int_0^x K(x - y, y) \, n(x - y, t) \, n(y, t) \, dy - n(x, t) \int_0^\infty K(x, y) \, n(y, t) \, dy. The first term counts the clusters of mass xx formed from two smaller ones, with the factor 12\frac12 because each pair is counted twice. The second term counts the clusters of mass xx lost by merging with any other cluster. It is a nonlinear integro-differential equation: a time derivative of nn and integrals of nn over mass.

Check for the constant kernel K=k>0K = k > 0: let N(t)=∫0∞n(x,t) dxN(t) = \int_0^\infty n(x, t) \, dx be the total number of clusters. Integrating over xx and exchanging the order of integration in the first term gives N′(t)=k2N2−kN2=−k2N2N'(t) = \frac{k}{2} N^2 - k N^2 = -\frac{k}{2} N^2. Hence N(t)=N(0)1+kN(0)t/2N(t) = \frac{N(0)}{1 + k N(0) t / 2}, so the number of clusters decreases like 2kt\frac{2}{kt}.

Remarks

For bounded kernels the total mass ∫0∞x n(x,t) dx\int_0^\infty x \, n(x, t) \, dx is conserved. For the product kernel K(x,y)=xyK(x, y) = xy the mass is conserved only up to a finite time, after which mass escapes into an infinitely large cluster; this is called gelation. The discrete version replaces the integrals by sums over integer cluster sizes.

Further reading

  1. Web https://en.wikipedia.org/wiki/Smoluchowski_coagulation_equation
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