Math 2.0

Integral equations Integro-differential equations Example

Population balance equation

Example

Let n(v,t)≥0n(v, t) \ge 0 be the number density of particles of volume v>0v > 0 at time tt in a well-mixed vessel. Let G(v)G(v) be the growth rate of a particle of volume vv, and let β(v,w)=β(w,v)≥0\beta(v, w) = \beta(w, v) \ge 0 be the aggregation kernel. Let S(v)≥0S(v) \ge 0 be the breakage rate. Let b(v∣w)b(v \mid w) be the density of fragments of volume vv produced when a particle of volume w>vw > v breaks. A population balance equation with growth, aggregation and breakage is ∂n∂t+∂∂v(G(v)n)=12∫0vβ(v−w,w) n(v−w,t) n(w,t) dw−n(v,t)∫0∞β(v,w) n(w,t) dw+∫v∞b(v∣w) S(w) n(w,t) dw−S(v) n(v,t).\frac{\partial n}{\partial t} + \frac{\partial}{\partial v}\big(G(v) n\big) = \frac12 \int_0^v \beta(v - w, w) \, n(v - w, t) \, n(w, t) \, dw - n(v, t) \int_0^\infty \beta(v, w) \, n(w, t) \, dw + \int_v^\infty b(v \mid w) \, S(w) \, n(w, t) \, dw - S(v) \, n(v, t). The left side is a transport equation in the internal coordinate vv. The right side lists birth and death of particles by aggregation and by breakage. It contains partial derivatives in tt and vv and integrals of nn in vv, so it is an integro-partial differential equation.

Check in two special cases. With G=0G = 0 and S=0S = 0 only aggregation remains, and the equation is the Smoluchowski coagulation equation in the volume variable. With β=0\beta = 0, S=0S = 0 and constant G=gG = g, the equation is ∂tn+g ∂vn=0\partial_t n + g \, \partial_v n = 0. It is solved by n(v,t)=n0(v−gt)n(v, t) = n_0(v - g t) for any initial profile n0n_0 that vanishes for v≤0v \le 0. Every particle grows at the same rate, and the profile moves to the right.

Remarks

In general the internal coordinate can be a vector of several properties, such as size, composition and age, and the particles can also move in physical space. Moment methods turn the equation into ordinary differential equations for the moments ∫vkn dv\int v^k n \, dv when the kernels allow it. Such equations are used for crystallization, emulsions, aerosols and cell populations.

Further reading

  1. Web https://en.wikipedia.org/wiki/Population_balance_equation
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